Li, Na, K, Mg, Zn, Al, and Ca Anode Interface Chemistries Developed by Solid-State Electrolytes
- Sep 26, 2023
- 1 min read
Updated: Dec 16, 2024
Advanced Science 10(32) 2304235
Sambhaji S. Shinde, Nayantara K. Wagh, Sung-Hae Kim, Jung-Ho Lee
Abstract
Solid-state batteries (SSBs) have received significant attention due to their high energy density, reversible cycle life, and safe operations relative to commercial Li-ion batteries using flammable liquid electrolytes. This review presents the fundamentals, structures, thermodynamics, chemistries, and electrochemical kinetics of desirable solid electrolyte interphase (SEI) required to meet the practical requirements of reversible anodes. Theoretical and experimental insights for metal nucleation, deposition, and stripping for the reversible cycling of metal anodes are provided. Ion transport mechanisms and state-of-the-art solid-state electrolytes (SEs) are discussed for realizing high-performance cells. The interface challenges and strategies are also concerned with the integration of SEs, anodes, and cathodes for large-scale SSBs in terms of physical/chemical contacts, space-charge layer, interdiffusion, lattice-mismatch, dendritic growth, chemical reactivity of SEI, current collectors, and thermal instability. The recent innovations for anode interface chemistries developed by SEs are highlighted with monovalent (lithium (Li+), sodium (Na+), potassium (K+)) and multivalent (magnesium (Mg2+), zinc (Zn2+), aluminum (Al3+), calcium (Ca2+)) cation carriers (i.e., lithium-metal, lithium-sulfur, sodium-metal, potassium-ion, magnesium-ion, zinc-metal, aluminum-ion, and calcium-ion batteries) compared to those of liquid counterparts.
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Great review on solid-state batteries! It's cool to see how interface chemistries are advancing. By the way, for highlighting key terms in posts like this, I sometimes use a free bold text generator to make things stand out on social media.
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I was intrigued by the mention of monovalent and multivalent cations like Li+, Na+, and Mg2+ in battery technologies; it's a mouthful of chemistry! Reading about solid-state electrolytes and dendritic growth was my casual subway read-who'd have thought battery science could be this fascinating? By the way, if you ever need unique names for planets, try the Planet Name Generator!